Ivan Haller
Applied Physics Letters
The kinetics of the vapor-phase thermal isomerization of hexafluorobicyclo[2.2.0]hexa-2,5-diene to hexafluorobenzene was studied in the high-pressure region in the temperature range of 35-76°. The reaction is clean and homogeneous and it follows first-order kinetics with a rate constant k = 1013,73±0,11 exp[(-28.45 ± 0.16 kcal)/RT] sec-1. The heat of reaction, measured approximately by differential scanning calorimetry in the liquid state, was found to be 51 ± 3 kcal/mol.
Ivan Haller
Applied Physics Letters
William R. Young, Ivan Haller, et al.
Journal of Organic Chemistry
Ivan Haller, R. Srinivasan
The Journal of Chemical Physics
Ivan Haller
Journal of Physical Chemistry