William G. Van der Sluys, Alfred P. Sattelberger, et al.
Polyhedron
By controlled substitution of Zn2+ for Ga3+ and Na+ on the cation sites in β″-Na-gallate, the negative charge on the spinel block, and, hence, the number of charge compensating mobile Na+ ions in the conduction plane, can be changed. The mobile Na+ concentration can be varied from 1.5 to 1.67 ions per conduction plane. The ionic conductivity is largest at these two terminal compositions, and falls to much lower values between. A super-cell domain model is proposed to explain the behavior. © 1981.
William G. Van der Sluys, Alfred P. Sattelberger, et al.
Polyhedron
Mark W. Dowley
Solid State Communications
Zelek S. Herman, Robert F. Kirchner, et al.
Inorganic Chemistry
Fernando Marianno, Wang Zhou, et al.
INFORMS 2021