Abstract
Macroscopic quantities of single-layer carbon nanotubes have recently been synthesized by cocondensing atomic carbon and iron group or lanthanide metal vapors in an inert gas atmosphere. The nanotubes consist solely of carbon, sp2-bonded as in graphene strips rolled to form closed cylinders. The structure of the nanotubes has been studied using high-resolution transmission electron microscopy. Iron group catalysts, such as Co, Fe, and Ni, produce single-layer nanotubes with diameters typically between 1 and 2 nm and lengths on the order of micrometers. Groups of shorter nanotubes with similar diameters can grow radially from the surfaces of lanthanide carbide nanoparticles that condense from the gas phase. If the elements S, Bi, or Pb (which by themselves do not catalyze nanotube production) are used together with Co, the yield of nanotubes is greatly increased and tubules with diameters as large as 6 nm are produced. Single-layer nanotubes are anticipated to have novel mechanical and electrical properties, including very high tensile strength and one-dimensional conductivity. Theoretical calculations indicate that the properties of single-layer tubes will depend sensitively on their detailed structure. Other novel structures, including metallic crystallites encapsulated in graphitic polyhedra, are produced under the conditions that lead to nanotube growth. © 1995.