Publication
Science
Paper

The odd-number cyclo[13]carbon and its dimer, cyclo[26]carbon

Abstract

Molecular rings of N carbon atoms (cyclo[N]carbons, or CN) are excellent benchmarking systems for testing quantum chemical theoretical methods and valuable precursors to other carbon-rich materials. Odd-N cyclocarbons, which have been elusive to date, are predicted to be even less stable than even-N cyclocarbons. We report the on-surface synthesis of cyclo[13]carbon, $C_{13}$, by manipulation of decachlorofluorene with a scanning probe microscope tip. We elucidated the properties of $C_{13}$ by experiment and theoretical modeling. $C_{13}$ adopts an open-shell configuration with a triplet ground state and a kinked geometry, which shows different extents of distortion and carbene localization depending on the molecular environment. Moreover, we prepared and characterized the $C_{13}$ dimer, cyclo[26]carbon, demonstrating the potential of cyclocarbons and their precursors as building blocks for carbon allotropes.