G. Will, N. Masciocchi, et al.
Zeitschrift fur Kristallographie - New Crystal Structures
Trivalent transition ions associate in pairs when doped in CsCdBr3 crystals. Using high resolution absorption and emission spectroscopy, we have measured the energy levels of Pr3+ : CsCdBr3 and determined their associated irreducible representations. From Zeeman measurements we obtained the g factor for the 1D2 multiplet (g⌈ = 0.9; g⊥ = 0) and the predictions of a sim crystal field model show that Pr3+ ions see mainly an octahedral contribution, plus a small C3v distortion. We also use these measurements to determine a value of the hyperfine interaction constant AJ(1D2 of 440 +- 150 MHz which is smaller than the value previously determined for Pr3+ : LaF3. © 1993.
G. Will, N. Masciocchi, et al.
Zeitschrift fur Kristallographie - New Crystal Structures
Imran Nasim, Melanie Weber
SCML 2024
A.B. McLean, R.H. Williams
Journal of Physics C: Solid State Physics
Fernando Marianno, Wang Zhou, et al.
INFORMS 2021