D.K. Roe, J.K. Sass, et al.
Journal of Electroanalytical Chemistry
Gaseous chlorine perchlorate, ClOClO3, is found to be a major photolysis product of chlorine dioxide (OClO). Experiments were performed at room temperature with both continuous wave (mercury lamp) and pulsed (XeCl UV laser) light sources. The technique of time-resolved IR spectral photography (TRISP) was used to monitor the growth of the strong 1282-cm-1 ClOClO3 IR band following the application of a single ∼35 ns long, ∼70 mJ/cm2, XeCl laser pulse to a mixture of ∼30 torr of OClO and ∼700 torr of N2. It was found that under these conditions this band forms with a time constant of ∼1 μs. A transient IR band of unknown origin at ∼1232 cm-1 was also observed to develop on the same time scale. © 1982 American Chemical Society.
D.K. Roe, J.K. Sass, et al.
Journal of Electroanalytical Chemistry
P.P. Sorokin, J.J. Wynne, et al.
Applied Physics Letters
C.T. Rettner, D.S. Bethune, et al.
The Journal of Chemical Physics
A.C. Dillon, K.M. Jones, et al.
Nature